Yellow flags ruined fast laps for a number of drivers, but not Charles Leclerc who went quickest in Free Practice 2 in Azerbaijan.
| Pos | Num | Driver | Team | Laps | Time | Diff |
| 1 | 16 | Charles Leclerc | Scuderia Ferrari | 23 | 1:43.224 | |
| 2 | 11 | Sergio Perez | Red Bull Racing | 21 | 1:43.472 | +0.248s |
| 3 | 1 | Max Verstappen | Red Bull Racing | 17 | 1:43.580 | +0.356s |
| 4 | 14 | Fernando Alonso | Alpine F1 Team | 22 | 1:44.142 | +0.918s |
| 5 | 55 | Carlos Sainz | Scuderia Ferrari | 24 | 1:44.274 | +1.050s |
| 6 | 10 | Pierre Gasly | Scuderia AlphaTauri | 25 | 1:44.315 | +1.091s |
| 7 | 63 | George Russell | Mercedes-AMG F1 Team | 25 | 1:44.548 | +1.324s |
| 8 | 22 | Yuki Tsunoda | Scuderia AlphaTauri | 24 | 1:44.567 | +1.343s |
| 9 | 31 | Esteban Ocon | Alpine F1 Team | 24 | 1:44.609 | +1.385s |
| 10 | 4 | Lando Norris | McLaren F1 Team | 23 | 1:44.771 | +1.547s |
| 11 | 5 | Sebastian Vettel | Aston Martin F1 Team | 26 | 1:44.781 | +1.557s |
| 12 | 44 | Lewis Hamilton | Mercedes-AMG F1 Team | 24 | 1:44.874 | +1.650s |
| 13 | 18 | Lance Stroll | Aston Martin F1 Team | 25 | 1:44.874 | +1.650s |
| 14 | 3 | Daniel Ricciardo | McLaren F1 Team | 24 | 1:45.059 | +1.835s |
| 15 | 77 | Valtteri Bottas | Alfa Romeo F1 Team | 25 | 1:45.115 | +1.891s |
| 16 | 24 | Zhou Guanyu | Alfa Romeo F1 Team | 23 | 1:45.264 | +2.040s |
| 17 | 20 | Kevin Magnussen | Haas F1 Team | 25 | 1:45.588 | +2.364s |
| 18 | 23 | Alex Albon | Williams Racing | 13 | 1:46.397 | +3.173s |
| 19 | 47 | Mick Schumacher | Haas F1 Team | 20 | 1:46.425 | +3.201s |
| 20 | 6 | Nicholas Latifi | Williams Racing | 25 | 1:47.218 | +3.994s |
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