Red Bull and Ferrari proved the class of the field in Free Practice 3 for the Formula 1 Azerbaijan Grand Prix.
| Pos | Num | Driver | Team | Laps | Time | Diff |
| 1 | 11 | Sergio Perez | Red Bull Racing | 17 | 1:43.170 | |
| 2 | 16 | Charles Leclerc | Scuderia Ferrari | 18 | 1:43.240 | +0.070s |
| 3 | 1 | Max Verstappen | Red Bull Racing | 14 | 1:43.449 | +0.279s |
| 4 | 55 | Carlos Sainz | Scuderia Ferrari | 19 | 1:43.596 | +0.426s |
| 5 | 4 | Lando Norris | McLaren F1 Team | 13 | 1:44.418 | +1.248s |
| 6 | 3 | Daniel Ricciardo | McLaren F1 Team | 19 | 1:44.476 | +1.306s |
| 7 | 10 | Pierre Gasly | Scuderia AlphaTauri | 20 | 1:44.491 | +1.321s |
| 8 | 63 | George Russell | Mercedes-AMG F1 Team | 16 | 1:44.573 | +1.403s |
| 9 | 31 | Esteban Ocon | Alpine F1 Team | 14 | 1:44.685 | +1.515s |
| 10 | 5 | Sebastian Vettel | Aston Martin F1 Team | 18 | 1:44.689 | +1.519s |
| 11 | 14 | Fernando Alonso | Alpine F1 Team | 14 | 1:44.842 | +1.672s |
| 12 | 44 | Lewis Hamilton | Mercedes-AMG F1 Team | 18 | 1:44.845 | +1.675s |
| 13 | 18 | Lance Stroll | Aston Martin F1 Team | 17 | 1:44.879 | +1.709s |
| 14 | 24 | Zhou Guanyu | Alfa Romeo F1 Team | 17 | 1:44.913 | +1.743s |
| 15 | 20 | Kevin Magnussen | Haas F1 Team | 16 | 1:44.919 | +1.749s |
| 16 | 22 | Yuki Tsunoda | Scuderia AlphaTauri | 19 | 1:44.964 | +1.794s |
| 17 | 23 | Alex Albon | Williams Racing | 16 | 1:45.479 | +2.309s |
| 18 | 47 | Mick Schumacher | Haas F1 Team | 19 | 1:45.532 | +2.362s |
| 19 | 77 | Valtteri Bottas | Alfa Romeo F1 Team | 17 | 1:45.574 | +2.404s |
| 20 | 6 | Nicholas Latifi | Williams Racing | 17 | 1:46.070 | +2.900s |
