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Charles Leclerc capped off a strong opening day in Monaco as Daniel Ricciardo’s rough start to 2022 continued.
| Pos | Num | Driver | Team | Laps | Time | Diff |
| 1 | 16 | Charles Leclerc | Scuderia Ferrari | 29 | 1:12.656 | |
| 2 | 55 | Carlos Sainz | Scuderia Ferrari | 31 | 1:12.700 | +0.044s |
| 3 | 11 | Sergio Perez | Red Bull Racing | 30 | 1:13.035 | +0.379s |
| 4 | 1 | Max Verstappen | Red Bull Racing | 32 | 1:13.103 | +0.447s |
| 5 | 4 | Lando Norris | McLaren F1 Team | 24 | 1:13.294 | +0.638s |
| 6 | 63 | George Russell | Mercedes-AMG F1 Team | 30 | 1:13.406 | +0.750s |
| 7 | 10 | Pierre Gasly | Scuderia AlphaTauri | 31 | 1:13.636 | +0.980s |
| 8 | 14 | Fernando Alonso | Alpine F1 Team | 30 | 1:13.912 | +1.256s |
| 9 | 5 | Sebastian Vettel | Aston Martin F1 Team | 31 | 1:14.059 | +1.403s |
| 10 | 22 | Yuki Tsunoda | Scuderia AlphaTauri | 26 | 1:14.134 | +1.478s |
| 11 | 20 | Kevin Magnussen | Haas F1 Team | 31 | 1:14.239 | +1.583s |
| 12 | 44 | Lewis Hamilton | Mercedes-AMG F1 Team | 28 | 1:14.267 | +1.611s |
| 13 | 77 | Valtteri Bottas | Alfa Romeo F1 Team | 27 | 1:14.468 | +1.812s |
| 14 | 23 | Alex Albon | Williams Racing | 32 | 1:14.486 | +1.830s |
| 15 | 24 | Zhou Guanyu | Alfa Romeo F1 Team | 22 | 1:14.525 | +1.869s |
| 16 | 18 | Lance Stroll | Aston Martin F1 Team | 28 | 1:14.623 | +1.967s |
| 17 | 47 | Mick Schumacher | Haas F1 Team | 32 | 1:14.894 | +2.238s |
| 18 | 31 | Esteban Ocon | Alpine F1 Team | 33 | 1:15.216 | +2.560s |
| 19 | 6 | Nicholas Latifi | Williams Racing | 32 | 1:16.276 | +3.620s |
| 20 | 3 | Daniel Ricciardo | McLaren F1 Team | 2 | 0:00.000 | 0 |
